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A Phenylosotriazole Rule for the Determination of the Configuration of Monosaccharides

โœ Scribed by Khadem, H. El

Book ID
126091980
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
141 KB
Volume
28
Category
Article
ISSN
0022-3263

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D-Glucose, D-mannose and L-rhamnose were reacted with a racemic mixture of 2-butanol, and the resulting alpha-glycosides were analyzed by 1H NMR with COSY and NOESY experiments. Conformational analysis of alpha-glycosidic bonds performed with molecular modeling and appropriate heteronuclear long-ran