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A perturbed generalized eigenvalue equation for the hydrogen molecular ion

✍ Scribed by M. R. Woodward


Publisher
John Wiley and Sons
Year
1972
Tongue
English
Weight
279 KB
Volume
6
Category
Article
ISSN
0020-7608

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✦ Synopsis


Abstract

The SchrΓΆdinger equation for the hydrogen molecular ion is written as a perturbed united atom which is then treated as a generalized eigenvalue equation. The ground state energy is calculated through third order for small internuclear distances.


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In this work, we show that the eigenvalues of the problem \[ \begin{cases}\left(\Delta^{2}+V(x)+\lambda\right) u(x)=0 & x \in \Omega \\ u(x)=\Delta u(x)=0 & x \in \partial \Omega\end{cases} \] are generically simple in the set of \(\mathcal{C}^{4}\) regular regions of \(\mathbb{R}^{n}, n \geq 2\).