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A perturbational molecular orbital analysis of the cycloaddition of 2-carbomethoxy-1, 4-benzoquinone to vinylcyclohexene

✍ Scribed by D. Pitea

Book ID: 119115942
Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 168 KB
Volume: 93
Category: Article
ISSN: 0166-1280
DOI: 10.1016/0166-1280(83)80124-9

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A perturbational molecular orbital analy

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✍ D. Pitea 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 273 KB

A new approach to the calculation of the

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## Abstract magnified image A new, simple synthesis of 5‐carbomethoxy‐4__H__‐1,2,3‐triazolo[1,5‐__a__][1]benzazepines from the reaction of several Baylis‐Hillman acetates of 2‐azidobenzaldehydes with alkynide Grignard reagents such as phenylethynyl‐, 1‐propynyl‐ and ethynylmagnesium bromides follo

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Heteroatom Influence on the π-Facial Selectivity of Diels−Alder Cycloadditions to 1-Oxa-4-thia-6-vinylspiro[4.5]dec-6-ene, 3-Methoxy-3-methyl-2-vinylcyclohexene, and 3-Methoxy-2-vinylcyclohexene †,‡

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A simple and efficient method for the synthesis of novel spiropyrrolidines has been accomplished by regioselective 1,3-dipolar cycloaddition reactions of an azomethine ylide generated by thermalring opening of cis-1-cyclohexyl-2-phenyl-3-benzoyl aziridine with various (E)-3-arylidene-4-chromanones.