✦ LIBER ✦
A perturbational interpretation of enolate alkylation: C/O selectivity and electrophile leaving group effect.
✍ Scribed by J.M. Lefour; P. Sarthou; G. Bram; F. Guibé; A. Loupy; J. Seyden-Penne
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- French
- Weight
- 163 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
We have studied ambident anion _l_ ethylation in DME at O'C (1) and observed there is no simple relationship between reactivity (kT) and selectivity ([C]/[O]
= kc/kg) on changing the leaving group.