✦ LIBER ✦
A perturbation molecular orbital approach to ionic solvation. A new multiparameter solvent correlation based on solvent ionization potentials and electron affinities.
✍ Scribed by Ralph C. Dougherty
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- French
- Weight
- 217 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
The recent appearance of several multiple parameter solvent correlations 2-4 praapted us to examine the potential of perturbation molecular orbital (PC401 theory as a guide to the properties of organic solvents. Solvent ion interactions must involve only second order and higher perturbations, otherwise a solvent-ion reaction would occur. In principle the expression for