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A parametric study of the terminal maleation of polypropylene through an Alder Ene reaction

✍ Scribed by M. R. Thompson; C. Tzoganakis; G. L. Rempel


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
184 KB
Volume
36
Category
Article
ISSN
0887-624X

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✦ Synopsis


A study of the parameters that affect the Alder Ene reaction with respect to the synthesis of a terminally anhydride-functionalized polypropylene was carried out over a temperature range of 220 -250°C using maleic anhydride concentrations of 2-12 mol equivalence with respect to the vinylidene group. As previously observed, a Lewis acid (i.e., SnCl 2 ⅐ 2H 2 O) had a catalytic effect on the reaction at these temperatures, thereby improving anhydride content in the polymer for short reaction times. Increased temperature and maleic anhydride concentration had a positive effect on improving the incorporation of the succinyl anhydride moiety at the terminal site in polypropylene. Lower SnCl 2 ⅐ 2H 2 O concentrations, likewise, improve the functionality of the product. The application of a second-order kinetic model to the measured succinyl anhydride results was not valid over the entire temperature range studied due to side reactions, particularly vinylidene isomerization, and homopolymerization of maleic anhydride. Ruthenium chloride has been examined as another possible catalyst candidate in the reaction and has been found to improve the level of anhydride incorporation in polypropylene compared to stannous chloride.


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