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A palladium-catalyzed intramolecular arene-triflate coupling for the synthesis of fluoranthenes and benzofluoranthenes

✍ Scribed by Joseph E. Rice; Zhen-Wei Cai


Book ID
104224771
Publisher
Elsevier Science
Year
1992
Tongue
French
Weight
301 KB
Volume
33
Category
Article
ISSN
0040-4039

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ChemInform Abstract: Palladium-Catalyzed
✍ Z. WANG; X. LU πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 33 KB πŸ‘ 1 views

Palladium-Catalyzed Intramolecular Alkyne-Ξ±,Ξ²-Unsaturated Carbonyl Coupling. A Formal Synthesis of (+)-Pilocarpine. -Pd-catalyzed enyne coupling of (E) or (Z) alkynoates (I) or (III) provides the alkenyl substituted lactones (II) highly stereoselectively. After esterification with (+)-dimethyltart