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A One-Pot Allylation–Hydrostannation Sequence with Recycling of the Intermediate Tin Waste

✍ Scribed by Ghosh, Banibrata; Amado-Sierra, Maria Del Rosario I.; Holmes, Daniel; Maleczka, Robert E.


Book ID
123613641
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
597 KB
Volume
16
Category
Article
ISSN
1523-7060

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The Pd 0 -catalyzed alkylation of 1 by sodiodimethylmalonate led to the formation of two tricyclic diastereomers 2a and 2b. The structure of the major endo diastereomer 2b has been Scheme 1. Pd 0 -catalyzed alkylation of allylic bicyclic diacetate 1 [a] E.