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A one-parameter thermal-caloric corresponding-states model

✍ Scribed by Philip A. Thompson; Friedhelm Becker


Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
633 KB
Volume
34
Category
Article
ISSN
0009-2509

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✦ Synopsis


complete reduced-form thermodynamic descnption m terms of a smgle mate& parameter has an hlstorlcal precedent m the Van der Waals equation A sundar complete descnptlon can be constructed by empmcally correlatmg the acenmc factor o and the Ideal-gas heat capacity c.'(T,) with the smgle parameter 2. = c,"(T,)IR, a characterlstIc heat capacity The resuitmg approxunate model represents an extensron of the correspondmg-states prmclpie, mcorporatmg both thermal and caloric mformation The model can be apphed by means of convenhonal equations of state and IS prunardy useful for studies of physical processes m w&h the (hypothetxcal) fluid medmm IS contmuously vaned Illustratrve apphcatlons are gwen


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