✦ LIBER ✦

A one-dimensional model for phonon-induced relaxation

✍ Scribed by I. Benjamin; William P. Reinhardt

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 584 KB
Volume: 135
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(87)87209-3

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✦ Synopsis

An improved one-dimensional model for phonon-induced relaxation in a low-temperature matrix is considered. The contribution of the local lattice modes are explicitly taken into account. The model is used for analyzing the influence of some molecular parameters on the relaxation rate. The model is capable of explaining the anomalous dependence of the relaxation rate of HCI in Kr and Xe matrices at 20 K, on the vibrational quantum number.

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