๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

A one-carbon homologation of carbonyl compounds to carboxylic acids, esters, and amides

โœ Scribed by Dinizo, Stephen E.; Freerksen, Robert W.; Pabst, W. Edward; Watt, David S.


Book ID
126310708
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
612 KB
Volume
99
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.


๐Ÿ“œ SIMILAR VOLUMES


Ligand exchange reaction of sulfoxides i
โœ Tsuyoshi Satoh; Hideaki Unno; Yasuhiro Mizu; Yasumasa Hayashi ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 624 KB

A novel two-step procedure for one-carbon homologation of methylesters to esters, thioesters, carboxylic acids and amides is described. Methylesters are reacted with lithium carbanion of chloromethyl phenyl sulfoxide to give a-chloro a-sulfinyl ketones in 70 to 90% yields. Potassium enolate of the a