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A Nuclear Magnetic Resonance Study of the Reversible Hydration of Aliphatic Aldehydes and Ketones. I. Oxygen-17 and Proton Spectra and Equilibrium Constants

✍ Scribed by Greenzaid, P.; Luz, Z.; Samuel, David.

Book ID
120014677
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
991 KB
Volume
89
Category
Article
ISSN
0002-7863

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Conformational studies by nuclear magnet
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✍ Lech Kozerski; Janusz DΔ…browski πŸ“‚ Article πŸ“… 1972 πŸ› John Wiley and Sons 🌐 English βš– 323 KB

The s-cis + s-trans equilibrium of several enamino ketones and aldehydes, has been evaluated based on the results of aromatic solvent induced shift measurements and of protonation of the title compounds. In contrast to cc,p-unsaturated ketones bearing no heteroatom, the A&,,,, value but not the A.83