✦ LIBER ✦
A nuclear magnetic dipolar relaxation study of the internal rotation associated with intramolecular hydrogen bonding
✍ Scribed by Mamoru Kamiya
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 487 KB
- Volume
- 174
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
A modified method usirig the jump model to describe the transition mechanism of internal rotation was developed to analyze the "C dipolar relaxation times depending on the internal rotation specified by the rotamer dependence ofthe geometrical factors of functional rotating group. The utility of this analytical method was shown by applying it to analyze the dipolar relaxation time of the "C nucleus of a model molecule caused by the dipolar interaction with the proton of hydroxyl group undergoing internal rotation perturbed by intramolecular hydrogen bonding.