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A Novel Type of Pentacoordinate Silicon Complexes and Unusual Ligand Coupling by Intramolecular Electron Transfer

✍ Scribed by Matthias Driess; Nicoleta Muresan; Klaus Merz

Publisher: John Wiley and Sons
Year: 2005
Tongue: English
Weight: 153 KB
Volume: 117
Category: Article
ISSN: 0044-8249
DOI: 10.1002/ange.200501997

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## Abstract New fascinating electronic features of the simple diketoamine chelate ligand HN[CH~2~C(__t__Bu)O]~2~ (1) are described. Unexpectedly, the corresponding trianionic amido‐dienolate form of 1 is capable of reducing main‐group metal atoms M after initial coordination and intramolecular L→M