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A novel type of catalysis of [2 + 2] cycloadditions: the dimerization of cyclopropenes to tricyclohexanes over zeolites

✍ Scribed by Albert J. Schipperijn; Joachim Lukas


Book ID
108383286
Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
95 KB
Volume
13
Category
Article
ISSN
0040-4039

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A strategy based upon a "cascade" of three consecutive cycloaddition reactions [3+2], [2+2+2] and [4+2] allowed a stereoselective and straightforward access to the phyllocladane basic skeleton in eight high yield steps starting from 1,5-hexadiyne.