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A novel transformation of 13-ls-hydroperoxy-9, 11-octadecadienoicacid

✍ Scribed by Mats Hamberg

Book ID
115738715
Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
677 KB
Volume
752
Category
Article
ISSN
0005-2760

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πŸ“œ SIMILAR VOLUMES

Vanadium-catalyzed transformation of 13(
Vanadium-catalyzed transformation of 13(S)-hydroperoxy-9(Z), 11(E)-octadecadienoic acid: Structural studies on epoxy alcohols and trihydroxy acids
✍ Mats Hamberg πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 English βš– 643 KB

Treatment of methyl 13(S)-hydroperoxy-9(Z),ll(E)-octadecadienoate with vanadium oxyacetylacetonate led to the formation of two diastereomeric ~,#-epoxy alcohols, i.e. methyl ll(R),12(R).epoxy-13(S)-hydroxy-9(Z)-octadecenoate and methyl ll(S),12(S)-epoxy-13(S)hydroxy-9(Z)-octadecenoate. The epoxy alc