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A Novel Total Synthesis of Indolo[2,3-b]naphthalene-6,11-diones.

✍ Scribed by Marcos Fernandez; Carlos Barcia; Juan C. Estevez; Ramon J. Estevez; Luis Castedo

Publisher
John Wiley and Sons
Year
2004
Weight
106 KB
Volume
35
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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## Abstract Condensation of __N__‐trimethylsilylindole with methyl __N__‐trimethylsilyloxymethylpyroglutamate is the best method to obtain methyl __N__‐indolylmethylpyroglutamate. Friedel‐Crafts cyclization of the corresponding acid yields a new ketone (1,2,3,5,11,11a‐hexahydroindolizino[7,6‐__b__]