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A Novel Titanium-Catalyzed Cyclization of Olefinic Iodoethers to Tetrahydrofurans.

โœ Scribed by Longhu Zhou; Toshikazu Hirao


Publisher
John Wiley and Sons
Year
2003
Weight
156 KB
Volume
34
Category
Article
ISSN
0931-7597

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Palladium-Catalyzed Intramolecular Cyclization of Olefinic Propargylic Carbonates and Application to the Diastereoselective Synthesis of Enantiomerically Pure (-)-ฮฑ-Thujone. -Pd/P(2-furyl)3 catalyzed title reactions afford intermediate palladium( alkenyl)bicyclo(3.1.0)hexanes, which can be trapped