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A Novel Tin-Free Procedure for Alkyl Radical Reactions

✍ Scribed by Luisa Benati; Rino Leardini; Matteo Minozzi; Daniele Nanni; Rosanna Scialpi; Piero Spagnolo; Samantha Strazzari; Giuseppe Zanardi


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
116 KB
Volume
43
Category
Article
ISSN
0044-8249

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pretation is supported by the significantly lengthened Si-C bonds (I99 pm compared with 187 pm for the single bond) and the expanded angle at the tertiary C atoms (C-C-C between 104.2 and 106.5", Si-C-C between 110.9 and 114.8"). The Si-Si distance in 1 corresponds to a Pauling bond order of 0.45 an