A Novel Synthesis of Isothiocyanates from Amines Using Triphenylphosphine/Carbon Tetrachloride
β Scribed by Furukawa, Isao; Abe, Noboru; Hashimoto, Shizunobu
- Book ID
- 121263233
- Publisher
- Informa UK (Taylor & Francis)
- Year
- 1987
- Weight
- 61 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0308-664X
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π SIMILAR VOLUMES
Alkyl and aryl amines are converted smoothly to the corresponding isothiocyanates via the dithiocarbamates in good to excellent yields using di-tert-butyl dicarbonate (Boc 2 O) and 1-3 mol % of DMAP or DABCO as catalyst. As most of the byproducts are volatile, the work-up involves simple evaporation
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