A Novel Synthesis of Amino Acid Derivatives of Phospholene Oxides.
✍ Scribed by Buchammagari Haritha; Valluru Krishna Reddy; Masaki Takahashi; Mitsuji Yamashita
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 21 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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## Abstract The synthesis of the novel 1‐(substituted phenoxy/phenyl)‐2‐phospholene and phospholane 1‐oxide derivatives, which are analogs of sugars having a phosphorus atom in place of the ring oxygen of normal sugars, is described. All of the synthesized derivatives are structurally characterized
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
## Abstract The reaction of enolates of α‐unsubstituted carboxamides 3 with diphenyl phosphorazidate (DPPA) and di(__tert__‐butyl) dicarbonate (‘Boc anhydride’) in THF at −78° yielded 2‐{[(__tert__‐butoxy)carbonyl]amino}carboxamides 5 (__Scheme 2__) which are derivatives of α‐amino acids. In this r