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A novel synthesis of allyl and benzyl selenides via Sm/SbCl3 system in aqueous media

✍ Scribed by Lu Gen-Liang; Zhang Yong-Min

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
216 KB
Volume
18
Category
Article
ISSN
0256-7660

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✦ Synopsis

Abstract

Allyl and benzyl selenides were synthesized via reactions of allyl and benzyl bromides and diselenides promoted by Sm/Sb‐Cl~3~ system in aqueous media in moderate to good yields.

πŸ“œ SIMILAR VOLUMES

A novel synthesis of allyl and propargyl
A novel synthesis of allyl and propargyl selenides in aqueous media promoted by indium
✍ Weiliang Bao; Yunfa Zheng; Yongmin Zhang; Jianqing Zhou πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 French βš– 114 KB

Allylic and propargyl bromides react smoothly with diorganyl diselenides in aqueous media to give allylic and propargyl selenides in moderate to good yields. The reaction need not be carried out in inert atmosphere. The speed is quicker than the same reactions in organic media.