✦ LIBER ✦

A novel sulfinylation of alkenes by tosyl cyanide with titanium(IV) chloride

✍ Scribed by Paul E. Morgan; Ray McCague; Andrew Whiting

Book ID: 104261677
Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 180 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(99)00894-1

No coin nor oath required. For personal study only.

✦ Synopsis

Tosyl cyanide is activated by titanium(W) chloride to generate a tolylsulfinyl chloride equivalent, which readily stereo-and regio-spec~cally adds to certain alkenes to provide ~chlorosulfoxides. These chlorides rapidly hydrolyse on silica gel to provide [J-hydroxysulfoxides

📜 SIMILAR VOLUMES

ChemInform Abstract: A Novel Sulfinylati

ChemInform Abstract: A Novel Sulfinylation of Alkenes by Tosyl Cyanide with Titanium(IV) Chloride.

✍ Paul E. Morgan; Ray McCague; Andrew Whiting 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 35 KB

Novel perfluoroalkylation of alkenes wit

Novel perfluoroalkylation of alkenes with perfluoroalkanesulphonyl chlorides catalysed by a ruthenium(II) complex

✍ Kamigata, Nobumasa; Fukushima, Takamasa; Terakawa, Yoshie; Yoshida, Masato; Sawa 📂 Article 📅 1991 🏛 Royal Society of Chemistry ⚖ 889 KB

A Novel Synthesis of 2,3-Dihydro-1H-thie

A Novel Synthesis of 2,3-Dihydro-1H-thieno[3,4-b]pyrroles via Ring Transformation of Cyclic Sulfonium Ylides by Titanium(IV) Chloride—Triethylamine System.

✍ Hiroshi Maruoka; Kenji Yamagata; Fumi Okabe; Yukihiko Tomioka 📂 Article 📅 2005 🏛 John Wiley and Sons ⚖ 21 KB

## Abstract For Abstract see ChemInform Abstract in Full Text.

A novel synthesis of 2,3-dihydro-1H-thie

A novel synthesis of 2,3-dihydro-1H-thieno[3,4-b]pyrroles via ring transformation of cyclic sulfonium ylides by titanium(IV) chloride-triethylamine system

✍ Hiroshi Maruoka; Kenji Yamagata; Fumi Okabe; Yukihiko Tomioka 📂 Article 📅 2005 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 89 KB

A series of cyclic sulfonium ylides 4a-h reacted with titanium(IV) chloride in the presence of triethylamine to give the corresponding fused 2,3-dihydro-1H-thieno [3,4-b]pyrroles 5a-h, via a ring opening and recyclization. In contrast, treatment of compounds 4a, 4b, 4e and 4f with titanium(IV) chlor