A novel strategy for the preparation of long chain branching polypropylene and the investigation on foamability and rheology
β Scribed by Shuzhao Li; Miaomiao Xiao; Yong Guan; Dafu Wei; Huining Xiao; Anna Zheng
- Book ID
- 113608439
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- English
- Weight
- 894 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0014-3057
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Polyethylene produced by a vanadium-based polymerization catalyst contains long-chain branching as determined by NMR and rheology, even though the polymer has very low levels of vinyl unsaturation. A new mechanism is proposed for the formation of the long-chain branching, which involves COH bond act
## Abstract The reactive extrusion of maleic anhydride grafted polypropylene (PPβgβMAH) with ethylenediamine (EDA) as coupling agent is carried out in a corotating twinβscrew extruder to produce long chain branched polypropylene (LCBPP). Part of PPβgβMAH is replaced by maleic anhydride grafted high