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A Novel Stereospecific Synthesis of Glycosyl Cyanides from 1,2- O -Sulfinyl Derivatives

✍ Scribed by Benksim, Abdelhafid; Beaupère, Daniel; Wadouachi, Anne


Book ID
118152028
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
54 KB
Volume
6
Category
Article
ISSN
1523-7060

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Triphenylmethylium perchlorate-catalysed glycosylation of 2-, 3-, 4-, and 6-Otrityl-D-glucose derivatives kith f?-D-glucopyranosyl thiocyanates bearing a nonparticipating substituent at O-2 affords stereospecific derivatives of a-D-glucosyl-D-glucose Creation of 1,2-cis-glycosidic linkages with a hi