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A Novel Stereoselective Synthesis of Maleate Derivatives via Palladium-Catalyzed Dicarboalkoxylation of Terminal Alkynes

✍ Scribed by Li, Jinheng; Jiang, Huanfeng; Jia, Lanqi


Book ID
127198782
Publisher
Taylor and Francis Group
Year
1999
Tongue
English
Weight
195 KB
Volume
29
Category
Article
ISSN
0039-7911

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πŸ“œ SIMILAR VOLUMES


ChemInform Abstract: A Novel Stereoselec
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In the case of the formation of compounds (IVa) and (Va) it is shown that the yield and isomeric ratio is influenced by the type of the base used and the amounts of the base and the alcohol.

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A novel method for stereospecific synthesis of conjugated alkenynes is suggested. The reaction of (E)-[13-(trifluoromethanemlfonyloxy)-l-alkenyl](phenyl) iodonium trifluoromethanesulfonate with terminal alkynes in the presence of catalytic amounts of dichloro(triphenylphosphine)palladium(II) and CuI

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