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A Novel Selective Aza-Morita–Baylis–Hillman (aza-MBH) Domino Reaction and Aza-MBH Reaction of N-Sulfonated Imines with Acrolein Catalyzed by a Bifunctional Phosphine Organocatalyst

✍ Scribed by Xiangtai Meng; You Huang; Ruyu Chen


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
221 KB
Volume
14
Category
Article
ISSN
0947-6539

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## Abstract A series of polyether dendritic chiral phosphine Lewis bases was synthesized, and successfully applied to the asymmetric aza‐Morita–Baylis–Hillman reaction of __N__‐sulfonated imines (__N__‐arylmethylidene‐4‐methylbenzenesulfonamides) with methyl vinyl ketone (MVK), ethyl vinyl ketone (