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A Novel Scandium Fluoride, [C2N2H10]0.5[ScF4], with an Unprecedented Tungsten Bronze-Related Layer Structure.

โœ Scribed by Nicholas F. Stephens; Alexandra M. Z. Slawin; Philip Lightfoot


Book ID
101959760
Publisher
John Wiley and Sons
Year
2004
Weight
73 KB
Volume
35
Category
Article
ISSN
0931-7597

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Using 1, 4, 8, 11-tetraazacyclotetradecane (cyclam) as a template, a new layered zinc phosphate Zn 4 (PO 4 ) 2 (HPO 4 ) 2 ' 0.5(C 10 H 28 N 4 ) ' 2H 2 O (de5ned as ZnPO-cyclam) with 12-ring cavities was synthesized under hydrothermal conditions in a molar ratio ZnO:P 2 O 5 :cyclam:H 2 O โ€ซุโ€ฌ 1:2.2:0.