A novel route to olefins from vicinal diols
โ Scribed by Liu, Zhengchun; Classon, Bjoern; Samuelsson, Bertil
- Book ID
- 121880739
- Publisher
- American Chemical Society
- Year
- 1990
- Tongue
- English
- Weight
- 354 KB
- Volume
- 55
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
A novel method is reported for the transformation of vicinal diols to olefins. This methodology consists in the conversion of iodothiocarbonates such as 16 to olefin 17 with phenyl lithium in excellent yield. Compounds 7 and 12 were prepared by this methodology in order to determine if they would be
High levels of asymmetry can be achieved in the osmium tetroxide cis-hydroxylation of olefins by employing (-)-(R,R)-N,N,N',N'-tetramethylcyclohexane-l,2-traos-diamine as a chiral ligand for the osmium. Osmium tetroxide oxidation of olefins is an excellent method for forming vicinal diols under mil