A Novel Route to Fulvene Complexes of Titanium—Diastereoselective Complexation of Pentafulvenes to Cyclopentadienyltitanium Fragments
✍ Scribed by Rüdiger Beckhaus; Arne Lützen; Detlev Haase; Wolfgang Saak; Jörg Stroot; Sigurd Becke; Jürgen Heinrichs
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 102 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0044-8249
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Ph 3 Ge) 2 Eu(THF) 4 (1 a) and (Ph 3 Ge) 2 Eu(DME) 3 (1 b) have been synthesized by reacting Ph 3 GeH with europium naphthalene, C 10 H 8 Eu(THF) 2 , in THF or DME, respectively. The reaction of Ph 3 GeH with C 10 H 8 [EuI(DME) 2 ] 2 in DME yielded Ph 3 GeEuI(DME) 2 (2). The addition of two equivale
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