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A novel reaction type promoted by aqueous titanium trichloride. Synthesis of allylic pinacols

โœ Scribed by Clerici, Angelo; Porta, Ombretta


Book ID
126942823
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
674 KB
Volume
48
Category
Article
ISSN
0022-3263

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Allylic and propargyl bromides react smoothly with diorganyl diselenides in aqueous media to give allylic and propargyl selenides in moderate to good yields. The reaction need not be carried out in inert atmosphere. The speed is quicker than the same reactions in organic media.