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A novel reaction of coordinated vinylidenes: coupling with hydrogen sulfide to give a ?1-thioaldehyde

✍ Scribed by Bianchini, Claudio; Glendenning, Lionel; Peruzzini, Maurizio; Romerosa, Antonio; Zanobini, Fabrizio


Book ID
115449985
Publisher
The Royal Society of Chemistry
Year
1994
Tongue
English
Weight
200 KB
Volume
19
Category
Article
ISSN
0022-4936

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A stereoselective route to alkenyl sulfi
✍ Yukio Hoshino; Tatsuo Ishiyama; Norio Miyaura; Akira Suzuki πŸ“‚ Article πŸ“… 1988 πŸ› Elsevier Science 🌐 French βš– 247 KB

The reaction of 9-alkyl-9-BBNs with 1-bromo-i-phenylthioethene or (E)-and (Z)-2-bromo-lphenylthio-1-alkenes takes place readily in the presence of Pd(PPh& and sodium hydroxide to afford stereodefmed vinylic sulfides in excellent yields.