A novel reaction of acetanilide with nitrobenzene in DMSO - an unusual solvent assisted regioselective aromatic nucleophilic substitution

Organometallic compounds in organic synt

Organometallic compounds in organic synthesis. An equivalent of aromatic nucleophilic substitution by reactions of tricarbonylcyclohexadienyliumiron salts with O-silylated enolates: a novel arylation in the 2-position of carbonyl compounds.

✍ Lawrence F. Kelly; Acharan S. Narula; Arthur J. Birch 📂 Article 📅 1980 🏛 Elsevier Science 🌐 French ⚖ 255 KB

surmnary: TricarbonylcycZohexudienyZiwniron sdts are synthetGaZZy equivaZent to specifieuZZy suhtituted phenyE cationa. More extensive ability to form carbon-carbon bonds with aromatic rings would enlarge the scope of useful synthetic methods.1 Nucleophilic substitution of aryl halides by carbon nuc

A novel reaction of acetanilide with nitrobenzene in DMSO - an unusual solvent assisted regioselective aromatic nucleophilic substitution

✦ Synopsis