## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
A novel rapid sulfoxidation of sulfides with cyclohexylidenebishydroperoxide
β Scribed by J. Jon Paul Selvam; V. Suresh; K. Rajesh; D. Chanti Babu; N. Suryakiran; Y. Venkateswarlu
- Publisher
- Elsevier Science
- Year
- 2008
- Tongue
- French
- Weight
- 108 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
Cyclohexylidenebishydroperoxide was successfully used as the oxygen source for the oxidation of sulfides to sulfoxides for the first time. The sulfoxides were obtained in good to high yields without any detectable over-oxidation to sulfones under normal conditions.
π SIMILAR VOLUMES
Asymmetric sulfoxidation by means of a chloroperoxidase from Caldariomyces fumago and hydrogen peroxide as the oxygen source was studied for a series of sterically well-defined substrates. The stereochemistry of the sulfoxidation was the same for all substrates studied. While 2,3-dihydrobenzo[b]thio
Thexylchloroborane-methyl sulfide complex selectively deoxygenated both aromatic and aliphatic sulfoxides to the corresponding sulfides in high yield and purity at Oo C without affecting some other reducible structures. The growing usefulness of organosulfur compounds in organic synthesis has been r
Potassium peroxymonosulfate oxidation of suffides to suffoxides occurs with high diastereosebctivky. In seeking a preparative process for the skfe chain of antibacterial CP-70,429, penem 1. we prepared the sulfoxkle side chain a as a 4:l mixture of ~6~6 and & sulfoxides by oxkfatbn of the sulfide 2