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A novel process for the catalytic polymerization of olefins in supercritical carbon dioxide

โœ Scribed by Maartje Kemmere; Tjerk de Vries; Marius Vorstman; Jos Keurentjes

Book ID
108309930
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
190 KB
Volume
56
Category
Article
ISSN
0009-2509

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The diastereoselective epoxidation of ol
The diastereoselective epoxidation of olefins in supercritical carbon dioxide
โœ Geoffrey R Haas; Joseph W Kolis ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 207 KB

Allylic alcohols are epoxidized with tea-butyl hydroperoxide in the presence ofa vanadyl salen oxo-transfer catalyst in supercritical CO~ The metal catalyst was prepared in a simple two step, Schiffbase reaction to form the salen ligand, followed by complexation to the vanadyl group. The epoxidation