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A Novel Phenol-Forming Reaction for Preparation of Benzene, Furan, and Thiophene Analogs of CC-1065/Duocarmycin Pharmacophores

✍ Scribed by Hideaki Muratake; Aki Hayakawa; Mitsutaka Natsume

Book ID: 104258088
Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 495 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)01786-3

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✦ Synopsis

A palladium-catalyzed intramolecular couplingreactionb&weenmethylketonesandtriflates wasdeveloped for preparation of phenolderivatives13, 14,and15 from10,11,and12 in highyields. Potentaotitumor suMances35, 36,and37wereprepared fronr13,14,and15. 01997 ElsevierScienceLtd.

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