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A Novel Organometallic Polymer of Osmium(0), [Os(2,2′-bipyridine)(CO)2]n: Its Electrosynthesis and Electrocatalytic Properties Towards CO2 Reduction

✍ Scribed by Sylvie Chardon-Noblat; Alain Deronzier; František Hartl; Joris van Slageren; Taasje Mahabiersing


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
279 KB
Volume
2001
Category
Article
ISSN
1434-1948

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Novel Complexes trans(Cl)-[Os(bpy)(CO)(C
✍ Sylvie Chardon-Noblat; Philippe Da Costa; Alain Deronzier; Taasje Mahabiersing; 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 139 KB 👁 1 views

Photoirradiation of the complex trans(Cl)-[Os(bpy)(CO) 2 Cl 2 ] in acetonitrile with λ Ն 320 nm light gives rise to substitution of a CO ligand, with the formation of trans(Cl)-[Os(bpy)-(CO)(CH 3 CN)Cl 2 ]. The bonding properties and redox reactions of the novel photoproduct were thoroughly investig