Novel Complexes trans(Cl)-[Os(bpy)(CO)(C
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Sylvie Chardon-Noblat; Philippe Da Costa; Alain Deronzier; Taasje Mahabiersing;
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Article
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2002
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John Wiley and Sons
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English
⚖ 139 KB
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Photoirradiation of the complex trans(Cl)-[Os(bpy)(CO) 2 Cl 2 ] in acetonitrile with λ Ն 320 nm light gives rise to substitution of a CO ligand, with the formation of trans(Cl)-[Os(bpy)-(CO)(CH 3 CN)Cl 2 ]. The bonding properties and redox reactions of the novel photoproduct were thoroughly investig