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A Novel One-Pot, Two-Step Synthesis of Polycyclic Indoles via Tandem Intramolecular Hydroamidation/Palladium-Catalyzed Annulation

✍ Scribed by Jianxiu Liu; Yongda Zhang; Guisheng Li; Frank Roschangar; Vittorio Farina; Chris H. Senanayake; Bruce Z. Lu


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
181 KB
Volume
352
Category
Article
ISSN
1615-4150

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✦ Synopsis


Abstract

A robust one‐pot process has been developed for the synthesis of a variety of polycyclic indole skeletons via a consecutive sequence of hydroamidation and palladium‐catalyzed annulation, from inexpensive 2‐chloroanilines bearing tethered acetylenes.