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A Novel Mode of Reactivity for Gold(I): The Decarboxylative Activation of (Hetero)Aromatic Carboxylic Acids

✍ Scribed by Josep Cornella; Martin Rosillo-Lopez; Igor Larrosa


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
260 KB
Volume
353
Category
Article
ISSN
1615-4150

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## Abstract Reactions of electron‐poor α‐haloketones with (__N__‐isocyanimino) triphenylphosphorane in the presence of aromatic carboxylic acids proceed smoothly at room temperature and in neutral conditions to afford disubstituted 1,3,4‐oxadiazole derivatives in high yields. © 2010 Wiley Periodica