A novel method for the synthesis of vicinal disulfonamides promoted by metallic samarium in aqueous media
โ Scribed by Xi Liu; Yunkui Liu; Yongmin Zhang
- Publisher
- Elsevier Science
- Year
- 2002
- Tongue
- French
- Weight
- 64 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
โฆ Synopsis
A new method to synthesize vicinal disulfonamides by reductive coupling of N-sulfonylimines in Sm/HCl/THF has been developed and various reaction conditions have been studied.
๐ SIMILAR VOLUMES
The reductive coupling cyclization of 1,I-dicyanoalkenes was performed with metallic samarium in saturated aqueous NH4CI-THF solution at room temperature. Sub-stoichiometric quantities of samarium could be employed and trans-isomer was the major product.
Allylic and propargyl bromides react smoothly with diorganyl diselenides in aqueous media to give allylic and propargyl selenides in moderate to good yields. The reaction need not be carried out in inert atmosphere. The speed is quicker than the same reactions in organic media.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.