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A Novel Method for the Determination of Propagation Rate Constants: Carbocationic Oligomerization of Isobutylene †

✍ Scribed by Roth, Michael; Mayr, Herbert

Book ID
120379022
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
226 KB
Volume
29
Category
Article
ISSN
0024-9297

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Novel substituted epoxide initiators for
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This article presents the first detailed account of the discovery that substituted epoxides can initiate the carbocationic polymerization of isobutylene. ␣-Methylstyrene epoxide (MSE), 2,4,4-trimethyl-pentyl-epoxide-1,2 (TMPO-1), 2,4,4-trimethylpentyl-epoxide-2,3 (TMPO-2), and hexaepoxi squalene (HE