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A novel mechanistic study of the radical copolymerization of styrene with citraconic anhydride via 13C n.m.r. spectroscopy

✍ Scribed by Paul G. Brown; Kiyohisa Fujimori

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
460 KB
Volume
35
Category
Article
ISSN
0032-3861

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## Abstract The composition and monomer unit sequence distribution of copolymers of __p__‐chlorostyrene (__p__‐CST) with citraconic (α‐methylmaleic) anhydride (CA) prepared in methyl ethyl ketone (MEK) at 50,0 ± 0,1°C were determined over a range of comonomer feed mole fractions using ^13^C NMR spe

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The configuration of citraconic (~-methylmaleic) anhydride units in styrene/citraconic anhydride copotymers prepared in methyl ethyl ketone at 50.0 + 0. V was determined over a wide range of comonomer feed compositions using ~3C-NMR spectroscopy. It was found that the ratio of Z (zusammen) to E (ent