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A novel “linch-pin” construction of dihydrojasmone a high yield synthesis of cis-jasmone

✍ Scribed by J.L. Herrmann; J.E. Richman; R.H. Schlessinger


Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
182 KB
Volume
14
Category
Article
ISSN
0040-4039

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✦ Synopsis


We have outlined in the preceeding communications the alkylation' and conjugate addition' behavior of a new class of carbonyl anion equivalents.


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A new method for the synthesis of meso-substituted porphyrins is described: reaction of 5,10,15,20-tetrabromoporphine magnesium complex with aryl or heteroaryl boronic acids in the presence of Pd(PPh 3 ) 4 gave meso-substituted porphyrins in yields up to 70%.