A novel lanthanide-induced rearrangement
β Scribed by Holton, Robert A.; Williams, Andrew D.
- Book ID
- 126417035
- Publisher
- American Chemical Society
- Year
- 1988
- Tongue
- English
- Weight
- 388 KB
- Volume
- 53
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
The addition of an acetyl radical on caryophyllene leads to formation of the four isomeric ketones 5-8 involving a novel rearrangement of the caryophyllene skeleton. The acid catalyzed rearrangement of caryophyllene 1 has been studied in detail'. The final re-\_ action products are clovene 2, caryo
The conformation of diphenyl sulphone and 3,4'-dichlorodiphenyl sulphone has been studied by the lanthanideinduced shift (LIS) technique. The lanthanide-sulphone complexation model was established using the conformationally rigid dibenzothiophene sulphone molecule. Several models were tried, includi