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A novel helical chain zinc(II) coordination polymer derived from both ferrocenecarboxylato and bibenzimidazolyl ligands: synthesis, crystal structure and properties

✍ Scribed by Gang Li; Zifeng Li; Hongwei Hou; Xiangru Meng; Yaoting Fan; Weihua Chen

Publisher: Elsevier Science
Year: 2004
Tongue: English
Weight: 144 KB
Volume: 694
Category: Article
ISSN: 0022-2860
DOI: 10.1016/j.molstruc.2004.03.020

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✦ Synopsis

A novel zinc(II) coordination polymer {[Zn(FcCOO)

) was obtained by the reaction of Zn(OAc) 2 •2H 2 O with bbbm and FcCOONa in methanol solution. The molecule reveals an infinite one-dimensional (1D) helical chain [Zn(bbbm)] n with the ferrocenecarboxylate anion as monodentate coordinating to the Zn ion. Its thermal and electrochemical properties were also investigated.

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