A novel group of highly hydroxylated steroids from the starfish Protoreaster nodosus
β Scribed by Raffaele Riccio; Luigi Minale; Spirydon Pagonis; Cosimo Pizza; Franco Zollo; Jacques Pusset
- Book ID
- 107857213
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 868 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4020
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π SIMILAR VOLUMES
A nom2 steroidal glycoside has been isolated from the starfish Protoreaster nodosus. The structure includes a 3B,5a,6B,8B,lScr,24S-hexahydroxysteroidal moiety and a sugar moiety [2-0-methyl-B-D-xylopyranosyl-(1 + 21-a-L-arabinofuranosyZ]which is glycosidicaZZy attached at C-24 of the aglycone.
Three novel sulphated polyhydroxylated steroids, named asterasterols A-C (1-3), have been isolated from an Antarctic starfish of the family Asteriidae and their structures elucidated by spectroscopic studies. Steroid 1 has the seven-membered 5-oxalactone B-ring; 2 and 3 are the corresponding 6-oxo s