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A novel Friedel-Crafts reaction of hindered ketones

✍ Scribed by Roberts, Royston M.; El-Khawaga, Ahmed M.; Roengsumran, Sophon


Book ID
126407074
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
545 KB
Volume
49
Category
Article
ISSN
0022-3263

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Novel friedel - crafts reactions of some
✍ Shashi B. Mahato; Nirup B. Mandal; Anil K. Pal; Swapan K. Mitra 📂 Article 📅 1987 🏛 Elsevier Science 🌐 French ⚖ 480 KB

The novel secondary Friedel-Crafts acylation products of the arenes, dimethyl resorcinol, m-xylene, m-methylanisole and m-chlorotoluene using dichloroacetylchloride and anhydrous AlCIs are described. The formation of the unexpected products has been shown to depend on the nucleophilicity of the aren