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A Novel Family of Onium Salts Based Upon Isonitroso Meldrum's Acid Proves Useful as Peptide Coupling Reagents

✍ Scribed by Ayman El-Faham; Ramon Subirós-Funosas; Fernando Albericio


Book ID
102176403
Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
239 KB
Volume
2010
Category
Article
ISSN
1434-193X

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✦ Synopsis


Abstract

A new family of uronium salts (HTMU, HMMU, and HDmPyMU) based on isonitroso Meldrum's acid (HONM) are reported as stand‐alone coupling reagents. Amide bond formation with the use of these reagents occurred more quickly than that with other uronium salts as a result of the presence of a neighboring group effect with a cyclic structure. Thus, these novel onium salts were often more effective in the acylation of poor nucleophiles and in the control of optical purity than related Oxyma‐ and benzotriazole‐based reagents. Among the HONM derivatives, HMMU showed the best performance in reducing racemization and assembling demanding sequences such as the Aib‐ACP decapeptide or analogues of Leu‐enkephalin pentapeptide. Furthermore, the scope and limitations of the use of HONM as an additive in combination with carbodiimides is discussed.