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A novel family of layered double hydroxides?[MAl4(OH)12](NO3)2�xH2O (M = Co, Ni, Cu, Zn)Electronic supplementary information (ESI) available: Indexing for hydrated materials and sample TGA trace for [ZnAl4(OH)12](NO3)1.8(CO3)0.1�2.5H2O. See http://www.rsc.org/suppdata/jm/b4/b409027f/

✍ Scribed by Fogg, Andrew M.; Williams, Gareth R.; Chester, Ryan; O'Hare, Dermot

Book ID
120400553
Publisher
Royal Society of Chemistry
Year
2004
Tongue
English
Weight
433 KB
Volume
14
Category
Article
ISSN
0959-9428

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Physical stability vs. chemical lability
Physical stability vs. chemical lability in microporous metal coordination polymers: a comparison of [Cu(OH)(INA)]n and [Cu(INA)2]n: INA = 1,4-(NC5H4CO2)Electronic supplementary information (ESI) available: 1. Structure determination summaries for compounds 1–3. 2. Powder X-ray diffraction patterns: (a) for 1 and (b) for 2 after prolonged heating at different temperatures, establishing framework stabilities and (c) showing transformation of polymer 2 to the molecular compound 3, after 12 h in H2O. Fig. S1: copper coordination environments in compounds 1–3. See http://www.rsc.org/suppdata/cc/b2/b201501n/
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