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A novel direct route to 2-deoxy-2-fluoro-aldoses and their corresponding derivatives

✍ Scribed by Martin Albert; Karl Dax; Jörg Ortner


Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
511 KB
Volume
54
Category
Article
ISSN
0040-4020

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Stereoselective synthesis of s-(2-deoxy-
✍ Joanna Borowiecka; Paweł Lipka; Maria Michalska 📂 Article 📅 1988 🏛 Elsevier Science 🌐 French ⚖ 623 KB

Addition oP C,F'-dialkylphosphorodithioic acids to fully protected 1,2-unsaturated hsxo-and pentopyranoses gives S-(2-deoxy-glycosyl)-phosphorodithioates 'P -OH RO' 'SH -# H /OR HS-l'OR 2 2 Scheme I 2oa the &\_-adducte. The observed Oc'/s ratio was 89:ll and 92:8, respectively. pllso in these cases